{"chrom":"\n\n<div class=\"span4\" id=\"imgs\">\n<div class=\" inner\">\n\t\t<a href=\"#\" class=\"back\">Back<\/a>\n\t\t<ul class=\"thumbnails\">\n\t\t<li class=\"row-fluid\"><div class=\"span10\"><a href=\"#\" id=\"chemistry\" class=\"imgHome expand\" title=\"NMR evidence of relevant back-donation in a platinum-olefin\"><span class=\"brd\"><span class=\"nnr\"><img src=\"uploads\/51b19e8a9687b\/pi backdonation.JPG\" \/><\/span><\/span><\/a><\/div><div class=\"span7\" style=\"text-align:center;\"><a style=\"margin-left:15px;color:#68B1DE;width:100%;font-size:12px;\" href=\"uploads\/51b19e8a9687b\/pi backdonation.JPG\" target=\"_blank\">Download uncompressed image<\/a><\/div><\/li>\t\t<li class=\"row-fluid\"><div class=\"span10\"><p style=\"margin:20px 13%;\">Click on image to enlarge.<\/p><\/div><\/li>\n\t\t<\/ul>\n\t\t\n\t<\/div>\n<\/div>\n<div class=\"span7\" id=\"desc\">\n\t<div class=\"inner\">\n\t<a href=\"\/index.php?r=site\/topdf&id=20\" style=\"color:#68B1DE;\" class=\"pull-right \">Export to pdf<\/a>\n\t<\/div>\n\t<div class=\" inner\" style=\"margin-top:20px\">\n\t\t\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">NMR evidence of relevant back-donation in a platinum-olefin<\/p>\n\t\t<p> 2004<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Author(s)<\/p>\n\t\t<p style=\"margin-left:15px;\"> Francesco Ruffo et al.<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Caption<\/p>\n\t\t<p style=\"margin-left:15px;\"> Portion of the 1H NMR spectrum of the drawn complex at 25\u00b0C in deuterochloroform<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Comments<\/p>\n\t\t<p style=\"margin-left:15px;\"> Significant shift at low frequencies of the coordinated styrene protons with respect to the free olefin<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Discovery<\/p>\n\t\t<p style=\"margin-left:15px;\"> Unprecedented pi-backdonation into the platinum-olefin bond prompted by the geometry and the electronic features of the ancillary ligands<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Bibliography<\/p>\n\t\t<p style=\"margin-left:15px;\"> Cavallo, L., Macchioni, A., Zuccaccia, C., Zuccaccia, D., Orabona, I., Ruffo, F., \u201cNeutral Square-Planar Olefin\/Alkyl Platinum(II) Complexes Containing a N,N'-Imino-Amide Ligand. Experimental and Theoretical Evidence of Relevant -Back-Donation in the Platinum-Olefin Bond\u201d Organometallics 2004, 23, 2137.<\/p>\n\t\t<p class=\"text-info\" style=\"font-size:20px;\">Email<\/p>\n\t\t<p style=\"margin-left:15px;\"> ruffo@unina.it<\/p>\n\t<\/div>\n<\/div>\n\n"}